Publications

Bold list numbers indicate sole or principal author.

Also, see recent and pending papers from the kinetics group, where you can download local copies when the law of the land permits.

In Preparation

1. A Correlation-Based Method for Quantitative Analysis of Multi-Component Spectral Data. (in prepraration), (N. M. Donahue).
2. H-Atom Transfer From Alkanes by Hydrogen Atoms, (in preparation), (H. Rypkema, J. S. Clarke, N. M. Donahue, and J. G. Anderson).
3. Hydroxyl Radical Initiated Oxidation of Isoprene and Butadiene, (in preparation), (M. Sprengnether, N. M.Donahue, K. L. Demerjian, and J. G. Anderson).
4. Reactions of OH with High Molecular Weight Cycloalkanes, (in preparation), (M. Sprengnether, N. M.Donahue, K. L. Demerjian, and J. G. Anderson).

2000

1. Constraining the Mechanism of OH + NO2 Using Isotopically Labeled Reactants: Experimental Evidence for HOONO Formation J. Phys. Chem. Hal Johnston Festschrift (submitted), (N. M. Donahue, M. K. Dubey, R. Mohrschladt, T. J. Dransfield, and J. G. Anderson). (pdf)
2. High Pressure Flow Reactor Product Study of the Reactions of HOx + NO2: The Role of Vibrationally Excited Intermediates J. Phys. Chem. Hal Johnston Festschrift (submitted), ( T. J. Dransfield, N. M. Donahue and J. G. Anderson). (pdf)
3. Near-Field Influence on Barrier Evolution in Symmetric Atom Transfer Reactions: A New Model for Two-State Mixing. J. Phys. Chem. Hal Johnston Festschrift (submitted), (H. A. Rypkema, N. M. Donahue, and J. G. Anderson). (pdf)
4. Unimolecular reaction versus collisional stabilization of vibrationally excited intermediates: mechanism of HOx formation in the gas-phase ozone-alkene reaction J. Phys. Chem. Hal Johnston Festschrift (submitted), ( J. H. Kroll, N. M. Donahue J. S. Clarke, J. G. Anderson and K. L. Demerjian). (pdf)
5. Revisiting the Hammond Postulate: The Role of Reactant and Product Ionic States in Regulating Barrier Heights, Locations, and Transition State Frequencies. J. Phys. Chem. Hal Johnston Festschrift (submitted), (N. M. Donahue).
6. An Experimental Method for Testing Reactivity Models: A High-Pressure Discharge-Flow Study of H + Alkene and Haloalkene Reactions, J. Phys. Chem. 104, 22, 5254, (J. S. Clarke, N. M. Donahue, J. H. Kroll, H. A. Rypkema, and J. G. Anderson).
7. Muitiple Excited States in a Two-State Crossing Model: Predicting Barrier Height Evolution for H + Alkene Addition Reactions, J. Phys. Chem. 104, 19, 4458, 2000, (J. S. Clarke, H. A. Rypkema, J. H. Kroll, N. M. Donahue, and J. G. Anderson).
8. Atmospheric Chemistry. The Encyclopedia of Global Change Oxford University Press, (in press), (N. M. Donahue).

1999

1. Fourier Transform Ultraviolet Spectroscipy of the A(2Pi3/2) -- X(2Pi3/2) Transition of BrO, J. Phys. Chem. (in press), (D. M. Wilmouth, T. F. Hanisco, N. M. Donahue, and J. G. Anderson).
2. Temperature and Pressure Dependent Kinetics of the Gas-Phase Reaction of the Hydroxyl Radical with Nitrogen Dioxide, GRL, 26, 687, 1999, (T. J. Dransfield, M. M. Sprengnether, K. K. Perkins, N. M. Donahue, J. G. Anderson, and K. L. Demerjian). (pdf).

1998

1. Reaction Kinetics of OH with Ethane, Propane, and Cyclopropane from 180K -- 360K: Defining Frontier Orbital Interactions, J. Phys. Chem. 102, 48, 9847, 1998, (J. S. Clarke, J. H. Kroll, N. M. Donahue, and J. G. Anderson).
2. Predicting Radical-Molecule Barrier Heights: the Role of the Ionic Surface, J. Phys. Chem. 102, 22, 3923, 1998, (N. M. Donahue, J. S. Clarke, and J. G. Anderson).
3. New Rate Constants for 10 OH Alkane Reactions from 300 - 400 K: an Assessment of Accuracy, J. Phys. Chem. 102, 18, 3121, 1998, (N. M. Donahue, J. G. Anderson, and K. L. Demerjian).
4. Direct Observation of OH Production from the Ozonolysis of Olefins, GRL, 25, 59, 1998, (N. M. Donahue, J. H. Kroll,, J. G. Anderson, and K. L. Demerjian). (pdf).

1997

1. A high pressure flow study of the reaction NOx + OH -> HONOx; Errors in the Falloff Region, JGR Atmospheres, 102, 6153, 1997, (N.M. Donahue, M.K. Dubey, R. Mohrschladt, K.L. Demerjian, and J.G. Anderson).
2. Isotope specific kinetics of hydroxyl radical (OH) with water (H2O): Testing models of reactivity and atmospheric fractionation, J. Phys. Chem., 101, 1494, 1997, (M.K. Dubey, R. Mohrschladt, N.M. Donahue, and J. G. Anderson).
3. Comment on: "The measurement of tropospheric OH radicals by laser-induced fluorescence spectroscopy during the POPCORN field campaign," by Hofzumahaus et al., and "Intercomparison of tropospheric OH radical measurements by multiple folded long path laser absorption and laser induced fluorescence," by Brauers et al., GRL, 24, 3039, 1997, (E.J. Lanzendorf, T.R. Hanisco, N.M. Donahue and P.O. Wennberg).

1996

1. Free radical kinetics at high pressure: A mathematical analysis of the flow reactor, J. Phys. Chem., 100, 5821, 1996, (N.M. Donahue, J. S. Clarke, K. L. Demerjian, and J. G. Anderson).
2. Reaction Modulation Spectoscopy: A New Approach to Quantifying Reaction Mechanisms, J. Phys. Chem., 100, 17855, 1996, (N.M.Donahue, K. L. Demerjian, and J. G. Anderson).

1993

1. In situ nonmethane hydrocarbon measurements on SAGA 3, JGR Atmospheres, 98, 16,915, (N.M. Donahue and R.G. Prinn)
2. Ozone observations and a model of marine boundary layer photochemistry during SAGA 3, JGR Atmospheres, 98, 16,955, (with Thompson, A.M.; Johnson, J.E.; Torres, A.L.; Bates, T.S.; Kelly, K.C.; Atlas, E.; Greenberg, J.P.; Yvon, S.A.; Saltzman, E.S.; Heikes, B.G.; Mosher, B.W.; Shashkov, A.A.; Yegorov, V.T.)

1992

1. Short Lived Biogenic Trace Gases, in Trace Gases and the Biosphere (B. Moore and D. Schimel, ed.), (F. Fehsenfeld et. al.)

1990

1. Non-methane hydrocarbon chemistry in the remote marine boundary layer, JGR Atmospheres, 95, 18,387, (N.M. Donahue and R.G. Prinn)

1985

1. Relationship between peroxyacetyl nitrate (PAN) and nitrogen oxides in the clean troposphere, Nature, 318, 347, (with H. L. Singh, B. A. Ridley, J. Shetter, F. Fehsenfeld, D. Fahey, D. Parrish, E. Williams, S. Liu, G. Hebler, and P. Murphy)